Product ID:PR-3451,PAINT REMOVER
MSDS Date:05/28/1991
FSC:8010
NIIN:00N012329
MSDS Number: BQPFR

ELDORADO CHEMICAL COMPANY, INC.

14350 LOOKOUT ROAD
SAN ANTONIO, TX 78265
US

Emergency Phone: 800-531-1088

Info Phone: 512-653-9323

Preparer: PAT E SMITH

Cage: 55208

ELDORADO CHEMICAL COMPANY, INC.

34837 SAN ANTONIO, TX 78265-4837 US

Telephone: 800-531-1088/ 210-653-2060

Cage: 55208

SODIUM CHROMATE.ACGIH TLV FOR WATER SOLUBLE CHROMIUM VI

CAS: 7775-11-3

RTECS: GB2955000

Fraction By Weight: 1.0%

OSHA PEL 0.1 MG(CRO3)/M3 C

ACGIH TLV: 0.05 MG(CR)/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHYLENE CHLORIDE (DICHLOROMETHANE)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 70%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANOL

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 1-3%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AMMONIA

CAS: 7664-41-7

RTECS: BO0875000

Fraction By Weight: 5-12%

OSHA PEL 50 PPM

ACGIH TLV: 25 PPM/35 STEL; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

KNOWN HUMAN

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

(ACGIH, A1, 1991). SUFF EVIDENCE OF CARCINOGENICITY

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

FULL

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CORROSIVE TO EYES ON CONTACT.CORROSIVE
TO SKIN.WILL CAUSE SCARRING WHICH DISAPPEARS IN 1-2 YEARS.ABSORBED
IN LUNGS,NO CUMULATIVE EFFECT.NO LONGTERM CHRONIC HAZARDS TO EYES
OR SKIN.
Explanation of Carcinogenicity:METHYLENE CHLORIDE:INSUFFICIENT EVID FOR
CARCIN IN HUMANS;SUFFICIENT EVID FOR CARCIN IN ANIMALS
(IARC,2B,1987). (SUPDAT)
Effects of Overexposure:EYES:SHORT EXPOSURE WILL CAUSE HAZY VISION
WHICH RETURNS TO NORMAL.SKIN:SLIGHT PAIN AND
DISCOMFORT.INGESTION:N/K .INHALATION:INDUCES
NARCOSIS,DIZZINESS,NAUSEA.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH W/ H2O FOR AT LEAST 15 MIN.SEEK MED
ATTN.SKIN:FLUSH W/ H2O FOR 10 MIN.WASH W/ SOAP & H2O.INGEST:CALL MD
IMMEDIATELY .INHAL:REMOVE TO FRESH AIR.IF UNCONSCIOUS,GIVE OXYGEN &
SEEK MEDICA L ATTENTION.MD NOTE:METHYLENE CHLORIDE HAS PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE A SIMILAR EFFECT IN HUMANS.USE ADRENERGICS (EPINEPHRINE)
(SEE SUPP)

Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE .CONTACT WITH FLAME MAY PRODUCE TOXIC
CHLORIDE FUMES AND/OR PHOSGENE GAS.

Spill Release Procedures:ALLOW TO EVAPORATE.SWEEP UP RESIDUE WITH
SAWDUST OR SWEEPING COMPOUND.
Neutralizing Agent:N/K

Handling and Storage Precautions:DO NOT USE IN CONFINED SPACES. DO NOT
HEAT. AVOID ALL SKIN CONTACT. NOT INTENDED FOR CONSUMER USE.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT MAY
CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . USE METHOD PRECLUDES
LONG ENOUGH EXPOSURE TO CAUSE ABSORPTION.

Respiratory Protection:NIOSH/MSHA APPROVED SELF CONTAINED BREATHING
APPARATUS REQUIRED IF PEL OR TLV IS EXCEEDED.
Ventilation:100 FEET/MINUTE
Protective Gloves:POLYETHYLENE
Eye Protection:CHEM WORKER GOGGLES.MAY ADD (SEE ING 7)
Other Protective Equipment:FULL WASHRACK GEAR.
Work Hygienic Practices:AVOID ALL SKIN CONTACT.
Supplemental Safety and Health
FIRST AID PROC: ONLY FOR LIFE-SUSTAINING USES IN HUMANS EXPOSED TO
METHYLENE CHLORIDE . EXPLAN OF CARCIN: ANTICIPATED TO BE CARC (NTP,
2, 1989). ACGIH A2=SUSP HUMAN CARCINOGEN (1991). KNOWN TO C AUSE
CANCER (CAL PROP 65, 1988). SODIUMCHROMATE: SUFF EVID OF HUM CARC
(IARC,1,1990). KNOWN CARC (NTP, 1, 1991) (ING 5)

HCC:C2
Boiling Pt:B.P. Text:115F,46C
Decomp Temp:Decomp Text:N/K
Vapor Pres:200 MMHG
Vapor Density:2 (AIR=1)
Spec Gravity:1.2 (WATER=1)
pH:12
Evaporation Rate & Reference:1,WATER=1
Solubility in Water:INSOL-DISPERSABLE
Appearance and Odor:VISCOUS,PUNGENT LIQUID.
Percent Volatiles by Volume:90

STRONG ALKALIS,STRONG ACIDS,STRONG OXIDIZERS,REACTIVE METALS.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:HCL,PHOSGENE .

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . USEPA HAZARDOUS WASTE NUMBERS U080,
D007, U154, U220.

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particular situation.